Showing posts with label moire. Show all posts
Showing posts with label moire. Show all posts

Sunday, February 2, 2025

Graphene's End


Since its discovery in 2004, graphene has been heralded as the wonder material of the 21st century, and has been featured here quite often. It's spawned a whole new field of science basically, and it's called metameterials science, based on what's called two-dimensional materials. Twenty years later, we've reached peak graphene, with the news now being taken over by all things -ene, such as goldene or borophene, as seen below:

'Better than graphene' material development may improve implantable technology
May 2024, phys.org
https://phys.org/news/2024-05-graphene-material-implantable-technology.html

Borophene - It's the new graphene, impregnated with boron atoms, which makes it do even crazier things than graphene.

via Pennsylvania State University: Teresa Aditya et al, Chiral Induction in 2D Borophene Nanoplatelets through Stereoselective Boron–Sulfur Conjugation, ACS Nano (2024). DOI: 10.1021/acsnano.4c01792

Image credit: I can find no other credits except for a "3D-news" but this image is possibly related to 2010 Nobel Prize winner Andre Geim, who discovered graphene at University of Manchester in 2004. 


Electric fields boost graphene's potential, study shows
Jun 2024, phys.org

From the home of graphene, Manchester University:
"We demonstrate that electric field effects can disentangle and accelerate electrochemical processes in 2D crystals. This could be combined with state-of-the-art catalysts to efficiently drive complex processes like CO2 reduction, which remain enormous societal challenges."

"Control of these processes gives our graphene devices dual functionality as both memory and logic gate. This paves the way for new computing networks that operate with protons. This could enable compact, low-energy analog computing devices."

via University of Manchester National Graphene Institute: Jincheng Tong et al, Control of proton transport and hydrogenation in double-gated graphene, Nature (2024). DOI: 10.1038/s41586-024-07435-8.


Post Script: Moiré lattices is where you go when graphene ends, so:
Twist-angle in moiré lattice controls valley polarization switching in heterostructures
May 2024, phys.org

In case you were wondering, "they demonstrated for the first time the dependence of valley polarization switching and polarization degree on the moiré period by twist engineering in electrically controlled transition metal dichalcogenide heterobilayers". 

via Institute of Physics of the Chinese Academy of Sciences and Prof. Xu Xiulai of Peking University: Danjie Dai et al, Twist angle–dependent valley polarization switching in heterostructures, Science Advances (2024). DOI: 10.1126/sciadv.ado1281

Wednesday, September 11, 2024

The Graphene Legacy


Graphene was first discovered around 2004, and since then it's changed the world of science in ways far greater than most materials ever discovered. But we're at the point now where it's time to move on. Seeing the word "graphene" in a headline is no longer enough to make you want to see what it's doing. 

There's graphene but made of gold (goldene), there's something better than graphene (made of boron nitride), and there's the moiré lattice phenomena, which seems about as mindblowing as graphene itself was twenty years ago. 

Here are a few examples of how we're going ahead into the post-graphene world, and from now on, news about graphene will be limited to make for other things:

Researchers put a new twist on graphite
Jul 2023, phys.org

Didn't see this one coming!

They placed a single layer of graphene on top of a thin, bulk graphite crystal, and then introduced a twist angle of around 1 degree between graphite and graphene. They detected novel and unexpected electrical properties not just at the twisted interface, but deep in the bulk graphite as well. The electrical properties of the whole material differed markedly from typical graphite.

"Though we were generating the moiré pattern only at the surface of the graphite, the resulting properties were bleeding across the whole crystal."

Also: "Interdimensional" means mixed dimensional materials, like embedding 2D graphene into 3D graphite.

via University of Washington, Osaka University and the National Institute for Materials Science in Japan: Matthew Yankowitz, Mixed-dimensional moiré systems of twisted graphitic thin films, Nature (2023). DOI: 10.1038/s41586-023-06290-3.


Navigating moiré physics and photonics with band offset tuning
Oct 2023, phys.org

They started with a mismatched silicon-based bilayer moiré superlattice and adjusted the band offset by varying the thickness of one layer of the superlattices, to find that the offset effectively controls the moiré flatbands.

via SPIE Society of Photo-Optical Instrumentation Engineers, University of Electronic Science and Technology of China, Anqing Normal University, Guangxi University, and Nankai University: Peilong Hong et al, Robust moiré flatbands within a broad band-offset range, Advanced Photonics Nexus (2023). DOI: 10.1117/1.APN.2.6.066001


Researchers create first functional semiconductor made from graphene
Jan 2024, phys.org

Where you been - world's first functional semiconductor made from graphene

via Georgia Institute of Technology: Walt de Heer, Ultrahigh-mobility semiconducting epitaxial graphene on silicon carbide, Nature (2024). DOI: 10.1038/s41586-023-06811-0. 


Unlocking exotic physics: Exploring graphene's topological bands in super-moiré structures
Apr 2024, phys.org

Super-Moiré all day 

They're sandwiching monolayer graphene between two bulk boron nitride layers to create a new structure known as a super-moiré structure (whereas regular moiré is just two graphene layers).

via National University of Singapore:  Mohammed M. Al Ezzi et al, Topological Flat Bands in Graphene Super-Moiré Lattices, Physical Review Letters (2024). DOI: 10.1103/PhysRevLett.132.126401.


A single atom layer of gold—researchers create goldene
Apr 2024, phys.org
https://phys.org/news/2024-04-atom-layer-gold-goldene.html

Goldene - a sheet of gold only a single atom layer thick

via Linköping University: Synthesis of goldene comprising single-atom layer gold, Nature Synthesis (2024). DOI: 10.1038/s44160-024-00518-4