Showing posts with label biomimetic. Show all posts
Showing posts with label biomimetic. Show all posts

Wednesday, September 18, 2024

Buildings, Bodies and Biocompatibility


How are ancient Roman and Mayan buildings still standing? Scientists are unlocking their secrets
Oct 2023, phys.org

There's 2,000-year-old concrete still looking like the day it was poured. And there's also the front steps of my friend's apartment that's been crumbling since the day it got repaired. 

What's the difference? 

Some of these ancient builders might have just gotten lucky, said Cecilia Pesce, a materials scientist at the University of Sheffield in England. They'd toss just about anything into their mixes, as long as it was cheap and available—and the ones that didn't work out have long since collapsed.

"They would put all sorts of things in construction," Pesce said. "And now, we only have the buildings that survived. So it's like a natural selection process."

But alas, there does seem to be a pattern:
In a study published earlier this year, Admir Masic, a civil and environmental engineer at the Massachusetts Institute of Technology, proposed that this power comes from chunks of lime that are studded throughout the Roman material instead of being mixed in evenly. Researchers used to think these chunks were a sign that the Romans weren't mixing up their materials well enough.

Instead, after analyzing concrete samples from Privernum -- an ancient city outside of Rome -- the scientists found that the chunks could fuel the material's "self-healing" abilities. When cracks form, water is able to seep into the concrete, Masic explained. That water activates the leftover pockets of lime, sparking up new chemical reactions that can fill in the damaged sections.
via MIT



Catalysis breakthrough yields self-cleaning wall paint that breaks down air pollutants when exposed to sunlight
Mar 2024, phys.org

The UV radiation creates free charge carriers in the particles, which induce decomposition of the trapped pollutants from air into small parts and their release. In this way, the pollutants are rendered harmless, but do not remain permanently attached to the wall paint. The wall color remains stable in the long term. The new particles work with ordinary sunlight by adding certain additional atoms to the titanium oxide nanoparticles, such as phosphorus, nitrogen, and carbon.

via Vienna University of Technology and Università Politecnica delle Marche: Qaisar Maqbool et al, Highly Stable Self-Cleaning Paints Based on Waste-Valorized PNC-Doped TiO2 Nanoparticles, ACS Catalysis (2024). DOI: 10.1021/acscatal.3c06203


Veins of bacteria could form a self-healing system for concrete infrastructure
Dec 2023, phys.org

Fiber reinforcement has been around since the first masons mixed horsehair into their mud. 

BioFiber - polymer fiber encased in a bacteria-laden hydrogel and a protective, damage-responsive shell. The team reports that a grid of BioFibers embedded within a concrete structure can improve its durability, prevent cracks from growing, and enable self-healing.

It uses biomineralizing bacteria, aka microbial-induced calcium carbonate precipitation.

via Drexel University: Mohammad Houshmand Khaneghahi et al, Development of a nature-inspired polymeric fiber (BioFiber) for advanced delivery of self-healing agents into concrete, Construction and Building Materials (2023). DOI: 10.1016/j.conbuildmat.2023.133765


New AI tool discovers realistic 'metamaterials' with unusual properties
Feb 2024, phys.org

They call it "inverse design"

"Tell us what you want to have as properties and we engineer an appropriate material with those properties. What you will then get is not really a material but something in-between a structure and a material, a metamaterial" 

via Delft University of Technology Department of Biomechanical Engineering: Helda Pahlavani et al, Deep Learning for Size‐Agnostic Inverse Design of Random‐Network 3D Printed Mechanical Metamaterials, Advanced Materials (2023). DOI: 10.1002/adma.202303481

AI Art - Regenerative Plant Researcher 2 - 2024

New all-liquid iron flow battery for grid energy storage
Mar 2024, phys.org

A commonplace chemical used in water treatment facilities has been repurposed for large-scale energy storage in a new battery design for an iron-based flow battery.

It stores energy in a unique liquid chemical formula that combines charged iron with a neutral-pH phosphate-based liquid electrolyte, or energy carrier. 

The chemical, nitrogenous triphosphonate, nitrilotri-methylphosphonic acid or NTMPA, is commercially available in industrial quantities because it is typically used to inhibit corrosion in water treatment plants.

via Pacific Northwest National Laboratory: Phosphonate-based Iron Complex for a Cost-Effective and Long Cycling Aqueous Iron Redox Flow Battery, Nature Communications (2024). DOI: 10.1038/s41467-024-45862-3


Biodegradable aerogel: Airy cellulose from a 3D printer
Apr 2024, phys.org

Using the most common biopolymer on Earth (cellulose), they created a cellulose-based, 3D-printable aerogel, made of nanofibers for viscosity and nanocrystals so that it flows more easily during extrusion. To turn the ink into an aerogel after printing, the researchers replace the pore solvent water first with ethanol and then with air, all while maintaining shape fidelity.

It's an extremely effective heat insulator, and it's biocompatible with living tissues and cells.

It also can be rehydrated and re-dried several times after the initial drying process without losing its shape or porous structure, so it can be stored and transported in dry form and only be soaked in water shortly before use.

via Swiss Federal Laboratories for Materials Science and Technology: Deeptanshu Sivaraman et al, Additive Manufacturing of Nanocellulose Aerogels with Structure‐Oriented Thermal, Mechanical, and Biological Properties, Advanced Science (2024). DOI: 10.1002/advs.202307921


Sunrise to sunset, a new window coating blocks heat, not view
Apr 2024, phys.org

Some window coatings work for a 90-degree angle. Yet at the hottest time of day, the sun's rays enter at oblique angles.

They fabricated a transparent window coating by stacking ultra-thin layers of silica, alumina and titanium oxide on a glass base, with a micrometer-thick silicon polymer added to enhance cooling power. To shuffle the layers into an optimal configuration the team used quantum computing, or more specifically, quantum annealing, and validated their results experimentally.

(Note: We're now using quantum computers to validate experiments, and this is kind of the real story here.)

via University of Notre Dame: Seongmin Kim et al, Wide-angle spectral filter for energy-saving windows designed by quantum annealing-enhanced active learning, Cell Reports Physical Science (2024). DOI: 10.1016/j.xcrp.2024.101847

AI Art - Regenerative Plant Researcher 3 - 2024

How buildings influence the microbiome and human health
Apr 2024, phys.org

Modern buildings have a significant influence on human microbial colonization, depending on their nature and degree of shielding from the environment, and that this aspect should be taken into account in future architecture in terms of healthy and microbiome-friendly building conditions.

Buildings interrupt contact with microorganisms from the environment.

Future architecture should restore permeability for microorganisms.

Buildings themselves must be viewed as complex organic systems in the sense of countless interdependent microbial communities, which also have an impact on the human metaorganism.

Taken together, this has negative consequences, for example by creating new niches for disease hosts and vectors in buildings, concentrating waste and toxic substances or reducing ventilation and the entry of sunlight.

According to the researchers, one aim could therefore be to plan and construct the built environment in future in such a way that the focus is not on complete isolation from the natural, microbial environment. On the contrary: buildings can be opened up to nature again and made more nature-friendly.

This can be achieved, for example, by using less toxic building materials and creating an overall greater structural permeability to external, particularly microbial, influences.

via Kiel University Collaborative Research Center 1182 Origin and Function of Metaorganisms and the Canadian Institute for Advanced Research in Toronto, Columbia University, University of Oregon, California Institute of Technology: Thomas C. G. Bosch et al, The potential importance of the built-environment microbiome and its impact on human health, Proceedings of the National Academy of Sciences (2024). DOI: 10.1073/pnas.2313971121


Intelligent liquid: Researchers develop metafluid with programmable response
Apr 2024, phys.org

This came out in April 2024 - How the hell was this not in any other headlines? This is literally the T-1000 

They developed a programmable metafluid with tunable springiness, optical properties, viscosity and can transition between a Newtonian and non-Newtonian fluid.

It's a suspension of small, elastomer spheres between 50 to 500 microns that buckle under pressure,  changing the characteristics of the fluid.

A new class of fluid.

With this metafluid, no sensing is needed. The liquid itself responds to different pressures, changing its compliance to adjust the force of the gripper to be able to pick up a heavy bottle, a delicate egg and a small blueberry, with no additional programming.

Also this line:

"We show that we can use this fluid to endow intelligence into a simple robot"
(Because that is exactly what we all want right now.)

via Harvard John A. Paulson School of Engineering and Applied Sciences:  Katia Bertoldi, Shell buckling for programmable metafluids, Nature (2024). DOI: 10.1038/s41586-024-07163-z.

Friday, August 2, 2024

Making Colors


Making colors is not easy. Actually, seeing colors isn't easy either - most creatures don't see the rainbow the way we do. There's even plenty of humans who can't "see" certain colors, blue being the last to be recognized and named in most cultures (if this is the first time you're hearing about this, just search this site with the term "color" and learn more). 

Colors are not easy to make, not by nature and certainly not by humans. If a tree, for example, makes a vibrant, jewelescent red color, it might be bright, but it won't last long. To make a color that's strong but that also lasts a long time, it usually takes either a lot of effort, or a lot of toxic materials, and usually both. Tyrian purple? Not easy. Fire engine red? Toxic. 

But once in a while, we figure out a way to break those rules, because humans are pretty good at that, in fact, it's kind of one of the things we do best. 

Nature's palette reinvented: New fermentation breakthrough in sustainable food coloring
Dec 2023, phys.org

It's a fermentation process that produces "betalain-type" food colors (betalanins give red beets their distinctive bright pinkish red color).

They used an oleaginous yeast Yarrowia lipolytica found in cheese, then performed metabolic engineering to optimize the cellular metabolism.

via Danmarks Tekniske Universitet Novo Nordisk Foundation Center for Biosustainability DTU Biosustain: Philip Tinggaard Thomsen et al, Beet red food colourant can be produced more sustainably with engineered Yarrowia lipolytica, Nature Microbiology (2023). DOI: 10.1038/s41564-023-01517-5

Totally unrelated image credit: AI Art - Holographic Pill Advertisement - 2024


Chemists create organic molecules in a rainbow of colors that could be useful as organic light-emitting diodes
Dec 2023, phys.org

Acenes are chains of benzene molecules that have unique optoelectronic properties for use as semiconductors, and can also be tuned to emit different colors of light. These researchers dope acenes with boron and nitrogen for better properties, but also add the ligand carbodicarbene to improve stability.

via MIT: Chun-Lin Deng et al, Air- and photo-stable luminescent carbodicarbene-azaboraacenium ions, Nature Chemistry (2023). DOI: 10.1038/s41557-023-01381-0


What makes urine yellow? Scientists discover the enzyme responsible
Jan 2024, phys.org

When red blood cells degrade after their six-month lifespan, a bright orange pigment called bilirubin is produced as a byproduct, and is secreted into the gut. "Gut microbes encode the enzyme bilirubin reductase that converts bilirubin into a colorless byproduct called urobilinogen. Urobilinogen then spontaneously degrades into a molecule called urobilin, which is responsible for the yellow color we are all familiar with."

via University of Maryland: BilR is a gut microbial enzyme that reduces bilirubin to urobilinogen, Nature Microbiology (2024). DOI: 10.1038/s41564-023-01549-x


Beetles living in the dark teach us how to make sustainable colors
Mar 2024, phys.org

Chitin, or insect exoskeleton, is Earth's second most abundant organic molecule, and is already approved for medical use.  

They created the color by manipulating the folding patterns of the structure, so this is a structural color approach as opposed to a dye or pigment. 

via Singapore University of Technology and Design: Akshayakumar Kompa et al, Large‐Scale Artificial Production of Coleoptera Cuticle Iridescence and Its Use in Conformal Biodegradable Coatings, Advanced Engineering Materials (2024). DOI: 10.1002/adem.202301713


Researchers advance pigment chemistry with moon-inspired reddish magentas
Apr 2024, phys.org

RED!
From the makers of YInMn blue who mixed black manganese oxide with other chemicals, then heated them in a furnace to nearly 2,400 degrees Fahrenheit.

The new pigments, which could be used as energy-efficient coatings for vehicles and buildings, are based on divalent chromium, Cr2+, and are the first to use it as a chromophore; chromophores are the parts of a molecule that determine color by reflecting some wavelengths of light while absorbing others.

Inspired by the divalent copper that serves as a chromophore in Egyptian blue, they replaced the divalent copper with divalent chromium, leading to durable, reddish magenta pigments. 

BTW - "Most of the magenta-colored pigments used today are organic chemicals and suffer from stability issues when exposed to ultraviolet rays and heat from the sun because they can break down organic chemical bonds. Inorganic magenta pigments are rare, and most require a significant amount of cobalt salts that are hazardous to both humans and the environment."

via Oregon State University: Anjali Verma et al, Cr2+ in Square Planar Coordination: Durable and Intense Magenta Pigments Inspired by Lunar Mineralogy, Chemistry of Materials (2024). DOI: 10.1021/acs.chemmater.4c00253

Post Script:
The role of history in how efficient color names evolve
Mar 2024, phys.org

The past color vocabulary of a language shapes its ability to evolve.

"Once you as a linguistic community have an efficient vocabulary, that starting point restricts the next possible efficient vocabulary that you could have when you introduce a new term," says Twomey, the first author. "As the vocabulary grows, the number of different vocabularies that you could move to is increasingly constrained."

(I call this the 'chips vs crisps' phenomenon)

They used Berlin and Kayes World Color Survey - 25 speakers from each of 110 languages asked to name the same set of 330 color stimuli. 

  • Green-blue and blue are quite susceptible to changes in meaning as new terms are added, whereas red, black, and yellow remain relatively stable in meaning.
  • A historical vocabulary would most likely split green-blue into separate terms whereas the de novo vocabulary is more likely to introduce light green or orange than pink.
  • In principle, we can infer what ancestral color vocabularies were and then compare that to the historical record.
  • An example he provides is that at certain points in history, certain commercial dyes were introduced that became economically important to a culture.

via University of Pennsylvania: Colin R. Twomey et al, History constrains the evolution of efficient color naming, enabling historical inference, Proceedings of the National Academy of Sciences (2024). DOI: 10.1073/pnas.2313603121

Thursday, July 28, 2022

Fractals Are the Future


Topological synchronization of chaotic systems
Apr 2022, phys.org

Topological Synchronization, the Zipper Effect, and Chaos Coupling:

As chaotic systems are being coupled, the fractal structures of the different systems will start to assimilate with each other, taking the same form, causing the systems to synchronize.

And to say another way, fractals emerge from chaos, and at the same time, they provide structure to the chaos, which allows it to snap into a higher order of complexity with other chaoses (I do hear someone saying this is a legit scrabble word).

Chaos is random and unpredictable. Scientists hate it. You have no way of knowing what the system is going to do. Like the three-body problem of three stars orbiting each other, one will eventually get kicked out, but you have no way of knowing how it will happen, you can only measure the probability.

They do follow the "strange attractor" pattern though, where if given enough time, a pattern will emerge, not exact, but a shape recognizable enough that you can make a better prediction. Pendulums do this, and the famous water wheel analogy does too, except that each time you do it, the pattern will be different, unique to the pre-existing conditions of that moment alone -- the pendulum will make a new attractor pattern every time you run it. 

But within that pattern are fractals, and it's the fractals of all the attractor patterns of all the chaotic systems out there that act as the bridge to synch them up.

They showed that as chaotic systems are being coupled, the fractal structures start to assimilate each other causing the systems to synchronize. If the systems are strongly coupled, the fractal structures of the two systems will eventually become identical, causing a complete synchronization between the systems.

They termed this phenomenon Topological Synchronization.

Above image credit: Cell Division - Pixabay - 2022


Cut to the David Byrne experiment, where he's trying to find backup dancers:
Noemie began with an exercise I’ve never forgotten. It consisted of four simple rules:
  • Improvise moving to the music and come up with an eight-count phrase. (In dance, a phrase is a short series of moves that can be repeated.)
  • When you find a phrase you like, loop (repeat) it.
  • When you see someone else with a stronger phrase, copy it.
  • When everyone is doing the same phrase the exercise is over.
It was like watching evolution on fast-forward, or an emergent lifeform coming into being. At first the room was chaos, writhing bodies everywhere. Then one could see that folks had chosen their phrases, and almost immediately one could see a pocket of dancers who had all adopted the same phrase. The copying had begun already, albeit just in one area. This pocket of copying began to expand, to go viral, while yet another one now emerged on the other side of the room. One clump grew faster than the other, and within four minutes the whole room was filled with dancers moving in perfect unison. 
-How Music Works, David Byrne, 2012 (p67-68)
 
And back again:
"When the two chaotic systems are weakly coupled, the process usually starts with only particular fractal structures becoming identical. These are sets of sparse fractals that rarely will emerge from the activity of the chaotic system.

Synchronization starts when these rare fractals take a similar form in both systems. To get complete synchronization there must be a strong coupling between the systems. Only then will dominant fractals, that emerge most of the time from the system's activity, also become the same. 

They called this process the Zipper Effect.
But does David Byre approve?

via Bar-Ilan University, Israel: Nir Lahav et al, Topological synchronization of chaotic systems, Scientific Reports (2022). DOI: 10.1038/s41598-022-06262-z
 
Post Script:
Think about how the complexity of neuron-firing in the brain is a chaotic system, and how fractals are at play here.

Fractal brain networks support complex thought
Oct 2021, phys.org

via Dartmouth College: High-level cognition during story listening is reflected in high-order dynamic correlations in neural activity patterns, Nature Communications (2021). DOI: 10.1038/s41467-021-25876-x

Can consciousness be explained by quantum physics? Research is closer to finding out
Jul 2021, phys.org

via Cristiane de Morais Smith and Xian-Min Jin at Shanghai Jiaotong University: Xu, XY., Wang, XW., Chen, DY. et al. Quantum transport in fractal networks. Nat. Photon. (2021).

And you know Isaac Asimov already got us there:
Isaac Asimov's Robot Dreams -- a robot named Elvex (LVX-1) is updated with "fractal geometry" because the offending young scientist though it would "produce a brain pattern with more complexity, possibly closer to that of a human". The robot begins to dream about self-preservation, in direct opposition to the Laws of Robots, and is subsequently killed ("killed").